Computational and Experimental Observation of Li-Ion Concentration Distribution and Diffusion-Induced Stress in Porous Battery Electrodes
A multiscale model of porous electrodes based on the Gibbs free energy is developed, in which the Li ion diffusion, diffusion-induced stress (DIS), and polydispersities of electrode particle sizes are considered. The relationships between the size polydispersities and the concentration profiles and DIS evolution are investigated numerically. Li ion distributions are verified by in situ observation of color changes in a commercial porous graphite electrode.