phase transition

Chiqun Zhang            Amit Acharya            Noel J. Walkington            Oleg D. Lavrentovich

Motivated by recent experiments, the isotropic-nematic phase transition in chromonic liquid crystals is studied. As temperature decreases, nematic nuclei nucleate, grow, and coalesce, giving rise to tactoid microstructures in an isotropic liquid. These tactoids produce topological defects at domain junctions (disclinations in the bulk or point defects on the surface). We simulate such tactoid equilibria and their coarsening dynamics with a model using degree of order, a variable length director, and an interfacial normal as state descriptors. We adopt Ericksen's work and introduce an augmented Oseen-Frank energy, with non-convexity in both interfacial energy and the dependence of the energy on the degree of order. A gradient flow dynamics of this energy does not succeed in reproducing some simple expected feature of tactoid dynamics. Therefore, a strategy is devised based on continuum kinematics and thermodynamics to represent such features. The model is used to predict tactoid nucleation, expansion, and coalescence during the process of phase transition. We reproduce observed behaviors in experiments and perform an experimentally testable parametric study of the effect of bulk elastic and tactoid interfacial energy parameters on the interaction of interfacial and bulk fields in the tactoids.

This paper uses the thermodynamic data of aqueous solutions of uncrosslinked poly(N-isopropylacrylamide) (PNIPAM) to study the phase transition of PNIPAM hydrogels.  At a low temperature, uncrosslinked PNIPAM  can be dissolved in water and form a homogenous liquid  solution.  When the temperature is increased, the solution separates into two liquid phases with different concentrations of the polymer.   Covalently crosslinked PNIPAM, however, does not dissolve in water, but can imbibe water and form a hydrogel.  When the temperature is changed

Physical gels are characterized by dynamic cross-linksthat are constantly created and broken, changing its state between solid andliquid under influence of environmental factors.

The electric-field-induced phase transition was investigated under mechanical confinements in bulk samples of an antiferroelectric perovskite oxide at room temperature. Profound impacts of mechanical confinements on the phase transition are observed due to the interplay of ferroelasticity and the volume expansion at the transition. The uniaxial compressive prestress delays while the radial compressive prestress suppresses it. The difference is rationalized with a phenomenological model of the phase transition accounting for the mechanical confinement.