Effect of External Normal and Parallel Electric Fields on 180^o Ferroelectric Domain Walls in PbTiO3
We impose uniform electric fields both parallel and normal to 180^o ferroelectric domain walls in PbTiO3 and obtain the equilibrium structures using the method of anharmonic lattice statics. In addition to Ti-centered and Pb-centered perfect domain walls, we also consider Ti-centered domain walls with oxygen vacancies. We observe that electric field can increase the thickness of the domain wall considerably. We also observe that increasing the magnitude of electric field we reach a critical electric field E^c; for E > E^c there is no local equilibrium configuration.