We present a new wrinkling-based measurement technique for quantifying the viscoelastic properties of confined polymer thin films. This approach utilizes real-time laser-light scattering to observe the kinetics of thermally-induced surface wrinkling, which evolves isothermally as a function of annealing time. Specifically, wrinkling is induced by applying a thermal stress to a polystyrene film that is sandwiched between a silicon substrate and an aluminium thin film superstrate. By following the time evolution of the wrinkle wavelength and amplitude, we can infer the rubbery modulus and shear viscosity of the polystyrene film with the aid of a theoretical model.

A thin film subject to compressive strain can either bend (for large strain gradient) or wrinkle (for small strain gradient). The bending is traditionally used in thermostats (bimetal stripes), but couple of years ago, it was extended to the nanoscale thin films which can bend and roll-up to tubes with defined number of rotations. The wrinkles are also rather common in macro- and microscale thin films.
Here, we developed an equilibrium phase diagram for the shape of
compressively strained free-hanging films by total strain energy
minimization.